The only time I've managed to damage an Avanti in this way (very similar marks on piston and damage to plating above the exhaust port) was when I seized it when holding it had prolonged high speeds in order to assess the setup. In my case I had already picked up on fuel starvation symptoms at prolonged high speed runs, which I was trying to resolve, forgetting that the carb type that I was using is well documented as having fuel starvation issues unless the carb is 'blueprinted' (enough of a clue for some of you).
Since the above issue I have modified the carb according and cured the fuel starvation issue. Frustrating that I only thought about it after the damage was done
You say that you held it open for a long period before the event happened, has the same setup been ridden like this without issue before? Any reason why you might be suffering fuel starvation? Anything changed from previous good running, just filled up, etc?
Regardless of the piston marks and plating damage near exhaust port, which are similar to the state of mine after the seizure, the wear to top of plating bore is odd (?).
Adam